Shampoo Formulation: pH Adjustment and Sulfate-Free Base Comparison

Asked by: bbaekhyunee0405 On: April 24, 2021 Product Type: Cosmetics

Question

I am formulating a shampoo with the following ingredients: Water, Sulfate Free Shampoo Base (ph.7), Glycerin, Mild Preserved Eco™, and Sodium Chloride. 1. If I want to adjust the pH to 5.5 but do not have a pH meter, what percentage of citric acid should I add? 2. What is the difference between Sulfate Free Shampoo Base and Sulfate Free No-Tear Shampoo Base?

Answer

Shampoo Formulation Questions

1. Adjusting pH without a pH meter

It is not possible to provide an exact percentage of citric acid needed to adjust the pH of your shampoo base to 5.5 without using a pH meter or pH strips. The amount of acid required depends on several factors, including the precise starting pH of your specific batch of base, the total volume of your mixture, and the buffering capacity of the other ingredients (like glycerin and the preservative).

Adding a fixed percentage could easily result in a pH that is too low (too acidic) or still too high. Both extremes can affect the performance, stability, and mildness of your shampoo.

Recommendation: To accurately and safely adjust the pH to 5.5, it is highly recommended to use a pH meter or reliable pH strips. You would typically prepare a dilute solution of citric acid and add it drop by drop or in small increments to your shampoo mixture, stirring well and measuring the pH after each addition until you reach your target pH of 5.5.

2. Difference between Sulfate Free Shampoo Base and Sulfate Free No-Tear Shampoo Base

Based on the product information, the main difference between the two bases lies in their intended use and gentleness, particularly regarding eye irritation:

  • Sulfate Free Shampoo Base (pH 7, Clear, Foaming): This is a general-purpose sulfate-free base suitable for shampoos, liquid soaps, facial cleansers, and other skin cleansing products. It provides good foaming and cleansing properties. Its typical pH range is 6.5-7.5.
  • Sulfate Free No-Tear Shampoo Base (pH 6, Clear, Foaming): This base is specifically developed to be extra gentle and has a "no-tear" property, meaning it is formulated to be non-irritating to the eyes. This makes it particularly suitable for products requiring high gentleness, such as baby shampoos and cleansers for sensitive areas. While it is very gentle, its cleaning efficiency might be slightly lower compared to the standard Sulfate Free Shampoo Base. Its typical pH range is also stated as 6.5-7.5 in the description, despite the name suggesting pH 6.

In summary, if you are making a product for babies or individuals with very sensitive eyes, the Sulfate Free No-Tear Shampoo Base is the more appropriate choice due to its non-irritating properties. For general adult shampoos or cleansers where the "no-tear" feature is not critical, the standard Sulfate Free Shampoo Base is suitable.