Formulating a Time-Released BHA Toner similar to Paula's Choice BHA 9
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How to Formulate a Time-Released BHA Toner similar to Paula's Choice BHA 9?
I am interested in creating a BHA toner formula that is similar to Paula's Choice BHA 9, which contains a high concentration of time-released salicylic acid (BHA) along with soothing and conditioning ingredients.
Based on the information provided, the process seems straightforward:
- Mix encapsulated salicylic acid (up to 6.6% concentration) in water to create a Timed-Release BHA Toner.
- Add other desired nourishing ingredients.
To make it similar to the popular Paula's Choice product, which uses ingredients like Avena Sativa (Oat) Kernel Extract, Boerhavia Diffusa Root Extract, Sea Whip Extract, and Arginine for soothing and conditioning, what are some suitable alternatives for these functions?
Suggested alternatives include:
- Anti-irritant: Beta Glucan, Vitamin B5, Bisabolol
- Conditioning agents: Hydrolyzed Vegetable Protein
- Moisturizing: Natural Moisturizing Amino Acids
It was also mentioned that a pure BHA toner using only encapsulated salicylic acid in water could be made, followed by applying a separate nourishing formula.
Key questions:
- What specific types of encapsulated or complexed salicylic acid are recommended for a leave-on formula like this (e.g., ActiveRelease™ Salicylic Acid, Complex Salicylic Acid powder)?
- What is the maximum allowed concentration for Salicylic Acid in over-the-counter cosmetics (noting that 6.6% of the 30% liquid type corresponds to 2% Salicylic Acid)?
- What are the recommended forms/sources for the suggested alternative ingredients (e.g., Avena sativa (Oat) Extract (Water Soluble), Beta Glucan (Saccharomyces cerevisiae extract), Beta Glucan 70% (Oat Extract, Water-Soluble), Beta Glucan 90% (Oat Extract, Water-Soluble), Panthenol (Vitamin B5, DL-Panthenol, Powder), D-Panthenol Care (Pro-Vitamin B5, 100% Liquid), Natural Bisabolol (Brazil Chamomile), Bisabolol (Alpha Bisabolol, Bisabolol RAC), Hydrolyzed Pea Protein, Natural Moisturizing Amino Acids)?
- What other standard formulation components (solvents, thickeners, stabilizers) are typically needed in such a toner (e.g., Propylene Glycol, PEGs, Water, Butylene Glycol, Polysorbate 20, Disodium EDTA)?
- Is pH adjustment necessary when formulating with encapsulated or time-released salicylic acid, and what is the recommended final pH range for stability and effectiveness (considering the note about pH around 5.0 during action)?
- What is the recommended formulation approach (e.g., dispersing BHA first, then adding others)?
- What kind of stability testing is recommended for the final formulation?
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Creating a Formula Similar to Paula's Choice BHA 9
To create a formula similar to Paula's Choice BHA 9, which features a high concentration of time-released salicylic acid (BHA) along with soothing and conditioning ingredients, you can focus on selecting key components that provide similar functions.
Key Ingredients and Alternatives
Timed-Release Salicylic Acid: The core active ingredient. Paula's Choice uses a 9% concentration of time-released salicylic acid. For DIY formulations, especially for leave-on products, using an encapsulated or complexed form of salicylic acid is recommended for gentler, timed release compared to standard salicylic acid. Options include:
- Encapsulated Salicylic Acid (available in liquid or powder forms suitable for leave-on, such as ActiveRelease™ Salicylic Acid or Complex Salicylic Acid powder types). Note that the liquid encapsulated type found in search (Encapsulated Salicylic Acid (Liquid, Timed-Release, Wash-Off)) is specifically for rinse-off products, but a leave-on liquid type also exists.
- The maximum allowed concentration for Salicylic Acid in over-the-counter cosmetics is typically 2% (which corresponds to 6.6% of the Encapsulated Salicylic Acid 30% liquid type).
Soothing and Anti-Irritant Ingredients: To counteract potential irritation from BHA, incorporating ingredients with calming properties is crucial. Based on the original formula and suggestions, consider:
- Avena Sativa (Oat) Kernel Extract: A known anti-irritant (e.g., Avena sativa (Oat) Extract (Water Soluble)).
- Beta Glucan: Excellent for strengthening skin and reducing irritation (e.g., Beta Glucan (Saccharomyces cerevisiae extract), Beta Glucan 70% (Oat Extract, Water-Soluble), Beta Glucan 90% (Oat Extract, Water-Soluble)).
- Vitamin B5 (Panthenol): Helps nourish skin, reduce inflammation, and support wound healing (e.g., Panthenol (Vitamin B5, DL-Panthenol, Powder), D-Panthenol Care (Pro-Vitamin B5, 100% Liquid)).
- Bisabolol: Derived from chamomile, known for its anti-irritant properties (e.g., Natural Bisabolol (Brazil Chamomile), Bisabolol (Alpha Bisabolol, Bisabolol RAC)).
Conditioning and Moisturizing Agents: Ingredients to improve skin feel and hydration.
- Glycerin: A common humectant.
- Arginine: An amino acid and skin-conditioning agent. Can be sourced individually or as part of a blend like Natural Moisturizing Amino Acids.
- Hydrolyzed Proteins: Such as Hydrolyzed Pea Protein, can act as conditioning agents.
- Natural Moisturizing Amino Acids: A blend mimicking the skin's natural moisturizing factors, providing hydration and supporting skin repair.
Solvents, Thickeners, Stabilizers: Ingredients like Propylene Glycol, PEGs, Water, Butylene Glycol, Polysorbate 20, and Disodium EDTA are standard formulation components used to create the desired texture, stability, and help dissolve other ingredients.
pH Adjustment
Yes, pH adjustment is important when formulating with salicylic acid. While standard salicylic acid requires a low pH (typically 3-4) for optimal exfoliation, which can be irritating, encapsulated or timed-release forms are designed to be gentler and may be effective at a slightly higher pH (the description for Encapsulated Salicylic Acid (Liquid, Timed-Release, Wash-Off) mentions a pH around 5.0 during action). However, the final pH of your formulation should still be within a range that ensures the stability and effectiveness of all ingredients, particularly the salicylic acid, and is suitable for skin application. You will likely need to adjust the pH of your final mixture using an acid (like citric acid or lactic acid solution) or a base (like sodium hydroxide solution) to achieve the desired range, typically between pH 4-5 for BHA products.
Formulation Approach
A simple approach, as suggested in the forum reply, is to first disperse or dissolve the encapsulated/complexed salicylic acid in water. Then, incorporate the soothing, conditioning, and moisturizing ingredients. Finally, add necessary solvents, thickeners, stabilizers, and adjust the pH. Always follow the specific mixing instructions and usage rates for each raw material.
Remember to perform stability testing on your final formulation.
ผลิตภัณฑ์ที่เกี่ยวข้องที่กล่าวถึง
Natural Bisabolol (Brazil Chamomile)
Panthenol (Vitamin B5, DL-Panthenol, Powder)
Natural Moisturizing Amino Acids (e.q. Prodew 400)
Beta Glucan (Saccharomyces cerevisiae extract)
Bisabolol (Alpha Bisabolol, Bisabolol RAC)
Complex Salicylic Acid (Powder, Water-Soluble)
D-Panthenol Care (Pro-Vitamin B5, 100% Liquid)
Hydrolyzed Pea Protein (High-Peptide)
Beta Glucan 70% (Oat Extract, Water-Soluble)
Beta Glucan 90% (Oat Extract, Water-Soluble)