Formulating Lightweight Waterproof Physical Sunscreen Serum: Ingredient Compatibility and Color Adjustment

Asked by: athip_1995 On: September 13, 2019 Product Type: Cosmetics Answered

Question

I want to formulate a physical sunscreen SPF 50 PA+++ that has a lightweight, serum-like base, is waterproof, contains some nourishing ingredients, absorbs oil, and provides slight coverage.

Can I use the following ingredients and percentages?

Emulsifier System:

  • 4% Light Lotion Maker
  • 5% Silicone Gel (Ultra Clear)
  • 5% Dimethicone 1Secs
  • 1% Pro Polymer™

Oil Absorption and Coverage:

  • 3% SelectSorb™
  • 5% QuikBlur™

Waterproofing:

  • 3% WaterGuard™ Ultra

Sunscreen Actives:

  • 10% Titanium Dioxide 15nm Liquid (Gloss)
  • 10% Zinc Oxide 35nm Liquid
  • 5% PMMA Booster

Color:

  • 0.3% Beige Iron Oxides EasyMix™
    • For different skin tones, what percentage should I use?

Nourishing and Antioxidant Ingredients:

  • 3% Squalane
  • 2% Niacinamide
  • 1% ActiveProtec™
  • 1% Ethyl Ferulate
  • 0.5% Magnesium Ascorbyl Phosphate
  • 0.1% Calcium Pantothenate
  • 0.05% Coenzyme Q10

Preservation System:

  • 3% 1,2-Hexanediol
  • 1% Mild Preserved Eco™
  • 0.2% Disodium EDTA

Answer

Formulation Feedback

Your goal is to create a light, serum-like physical sunscreen with SPF 50 PA+++, water resistance, oil absorption, slight coverage, and some beneficial skincare actives. The combination of ingredients you've selected aims to achieve these properties.

Emulsifier System

You are proposing a complex system using Light Lotion Maker, Silicone Gel (Ultra Clear), Dimethicone 1Secs, and Pro Polymer™.

  • Light Lotion Maker is an emulsifier suitable for creating light textures and can work in both hot and cold processes. It is designed to emulsify oils.
  • Silicone Gel (Ultra Clear) and Dimethicone 1Secs are silicone-based ingredients that contribute to a smooth, light, non-greasy feel and aid in spreadability. Dimethicone 1Secs is volatile, providing a quick-drying sensation.
  • Pro Polymer™ is a water-phase thickener that creates a gel texture in the water portion of a formula.

The physical sunscreen actives, Titanium Dioxide 15nm Liquid and Zinc Oxide 35nm Liquid, are specifically developed for water-in-oil (W/O) emulsion systems. Light Lotion Maker can function as a W/O emulsifier. Combining an oil/silicone phase emulsifier (Light Lotion Maker) with silicone emollients (Silicone Gel, Dimethicone 1Secs) and a water-phase thickener (Pro Polymer™) can potentially create a stable, lightweight emulsion, possibly a W/Si (water-in-silicone) or a complex W/O system with a thickened external water phase. This approach can help achieve the desired light, serum-like feel while incorporating the oil-soluble/dispersible components and the water-soluble actives. However, the interaction between the water-soluble Pro Polymer™ and the oil/silicone phase, as well as the stability of the emulsion type formed, will require careful formulation and testing.

Color Adjustment

You asked about the percentage of Beige Iron Oxides EasyMix™ for different skin tones.

  • 0.3% Beige Iron Oxides EasyMix™ will likely provide a very sheer tint suitable only for very fair skin tones or for slightly adjusting the base color without significant coverage.
  • To achieve a range of shades for different skin tones, you will need to adjust the percentage of Beige Iron Oxides EasyMix™ and incorporate other Iron Oxides EasyMix™ pigments, specifically Yellow, Red, and Black.
  • The product description for Beige Iron Oxides EasyMix™ provides example ratios for different shades (No. 1, No. 2, No. 3) by combining Beige, Yellow, Red, and Black Iron Oxides with Titanium Dioxide. These examples demonstrate that a single color pigment is not sufficient for a universal tint; blending is necessary to match various complexions. You will need to experiment with the ratios of these pigments to create the desired shades and coverage levels.

Other Ingredients

Conclusion

The proposed formulation has the potential to create a lightweight, waterproof physical sunscreen serum with added skincare benefits. The emulsifier system is complex but could yield the desired texture with careful formulation. Achieving different skin tones will require blending multiple Iron Oxide pigments. Pay close attention to the potential pH incompatibility of Niacinamide and Magnesium Ascorbyl Phosphate and the potential instability of the Titanium Dioxide dispersion in the presence of electrolytes like Disodium EDTA. Thorough testing of the final formulation for stability, SPF/PA efficacy, water resistance, and sensory properties is highly recommended.