How to determine which ingredients can be removed from a formulation
Question
I want to understand how to determine which ingredients in a cosmetic formulation are essential and cannot be removed, and which ones might be optional.
What are the different categories of ingredients, what are their functions, and how can I evaluate their necessity when developing or modifying a formula?
Answer
Subject: How to determine which ingredients can be removed from a formulation
Understanding which ingredients can be removed from a cosmetic formulation requires understanding the function of each ingredient. Formulations are complex systems where each component plays a role in the product's performance, stability, safety, and sensory properties.
Here's a breakdown of common ingredient categories and how to think about their necessity:
Base or Vehicle: (e.g., Water, Oils, Silicones)
- These make up the bulk of the product and determine its fundamental type (e.g., water-based serum, oil-based balm, emulsion cream).
- Necessity: Generally essential. You cannot remove the base without fundamentally changing the product type and function.
Active Ingredients: (e.g., specific extracts, vitamins, peptides)
- These are included to provide the primary claimed benefit of the product (e.g., moisturizing, anti-aging, soothing, cleansing agents in a cleanser).
- Necessity: Essential for the product to deliver its promised results. Removing an active ingredient will reduce or eliminate that specific benefit.
Supporting Ingredients / Additives: This is a broad category with various critical roles:
- Emulsifiers: (e.g., Glyceryl Stearate SE, PEG-10 Dimethicone) Needed to mix oil and water phases in emulsions (like creams and lotions) and keep them from separating.
- Necessity: Essential for stable emulsions. Removing emulsifiers will cause the product to separate.
- Thickeners / Gelling Agents: (e.g., Stearic Acid, Polyquaternium-7, Carbomer) Control the viscosity and texture of the product.
- Necessity: Essential for achieving the desired consistency and feel. Removing them will make the product too thin.
- Preservatives: (e.g., Phenoxyethanol, Methylparaben, Propylparaben, Potassium Sorbate) Prevent the growth of bacteria, mold, and yeast, especially in products containing water.
- Necessity: CRITICAL for safety. Removing preservatives from water-containing products is dangerous and can lead to microbial contamination, potentially causing skin infections.
- Stabilizers: (e.g., Disodium EDTA) Help maintain the product's integrity, prevent degradation, or improve the performance of other ingredients.
- Necessity: Often essential for long-term stability and shelf life.
- pH Adjusters: (e.g., Potassium Hydroxide) Ensure the product is at a suitable pH for skin compatibility, ingredient efficacy, and stability.
- Necessity: Often essential for safety, efficacy, and stability.
- Humectants: (e.g., Glycerin, Butylene Glycol) Attract and hold water, contributing to hydration and product feel.
- Necessity: Essential in moisturizing products for hydration. Also contribute to texture.
- Surfactants: (e.g., Stearic Acid, Myristic Acid, Lauric Acid, Potassium Hydroxide - these fatty acids react with KOH to form soap, a surfactant) In cleansers, these create lather and remove dirt/oil.
- Necessity: Essential for the cleansing function.
- Sensory Modifiers: (e.g., Silicones like Cyclopentasiloxane, emollients, film formers) Improve the feel, spreadability, or finish on the skin.
- Necessity: Essential for the desired user experience and texture.
- Aesthetics: (e.g., Fragrance, Colorants) Added for smell or appearance.
- Necessity: Not essential for the product's core function or safety, but important for consumer appeal. These are often the first ingredients considered for removal in "minimalist" formulations, but removing fragrance can sometimes reveal unpleasant base odors.
- Emulsifiers: (e.g., Glyceryl Stearate SE, PEG-10 Dimethicone) Needed to mix oil and water phases in emulsions (like creams and lotions) and keep them from separating.
Thinking Process:
- Identify the Product's Purpose: What is this product supposed to do (cleanse, moisturize, treat acne, etc.)?
- Identify Ingredient Functions: For each ingredient, determine its primary role(s) in the formulation. This requires knowledge of cosmetic ingredients.
- Categorize: Group ingredients by function (Base, Active, Additive - specifying the type of additive).
- Evaluate Necessity:
- Is this ingredient essential for the product type or base?
- Is it essential for the main claimed benefit (active)?
- Is it essential for safety (preservative)?
- Is it essential for stability (emulsifier, stabilizer, pH)?
- Is it essential for the basic function (surfactant in cleanser, thickener for desired viscosity)?
- Are there multiple ingredients serving a very similar role (e.g., several emollients or humectants)? Sometimes combinations are used for specific properties or synergy. Removing one might be possible, but requires careful consideration and testing to ensure the desired properties are maintained.
- Consider Interactions: Ingredients can affect each other. Removing one might impact the stability or performance of others.
- Testing is Crucial: Simply removing an ingredient based on a guess can ruin the product. Any change requires testing for stability, efficacy, safety, and sensory properties.
In summary, determining which ingredients can be removed is not about cutting "unnecessary" items arbitrarily. It's about understanding the complex interplay of ingredients and their specific roles in achieving a safe, stable, effective, and pleasant-to-use product. Ingredients like preservatives, emulsifiers (in emulsions), and primary surfactants (in cleansers) are typically essential for the product's integrity and safety. Others might be modified or potentially removed, but only with careful consideration and testing.