Polyglyceryl-4 Caprate: Simple Micellar Water Formulation, HLB, and Sensitive Skin Suitability

Asked by: Anonymous On: October 09, 2025 Product Type: Cosmetics

Question

I plan to purchase Polyglyceryl-4 Caprate and want to create a simple makeup remover/cleansing solution.

  • Is it possible to mix Polyglyceryl-4 Caprate solely with water and glycerin to effectively create a cleansing water and remove makeup?
  • I am concerned that the HLB value of Polyglyceryl-4 Caprate might be too high, potentially causing irritation for my sensitive skin.
  • Could you confirm the estimated HLB value for Polyglyceryl-4 Caprate?

Answer

That's a great choice for a gentle cleanser!

  1. Simple Formulation: Yes, mixing Polyglyceryl-4 Caprate with water and glycerin is an excellent and common way to create a simple, effective cleansing water or micellar water. The Polyglyceryl-4 Caprate acts as the cleansing agent/solubilizer, water is the solvent, and glycerin is a humectant to prevent dryness. We recommend a starting usage rate of around 5% for the Polyglyceryl-4 Caprate, as suggested in the product description.
  2. HLB and Sensitivity: You are correct that Polyglyceryl-4 Caprate is a high HLB surfactant, typically estimated to be in the range of 13-15. However, you should not be concerned about it being too harsh for sensitive skin. This ingredient is specifically chosen and marketed as a gentle, PEG-free alternative to traditional cleansing agents (like PEG-6 Caprylic/Capric Glycerides). Its mildness is why it is a key ingredient in many commercial micellar waters and cleansing products designed for sensitive skin, as noted in the product description examples.

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