Water Essence Formulation: Reducing Stickiness and Adjusting Low pH of High Concentration Vitamin C and Lycopene

Asked by: piyathidakr On: December 02, 2016 Product Type: Cosmetics

Question

I have formulated a water essence with the following ingredients:

  • L-Ascorbic Acid: 15%
  • Lycopene: 5%
  • Propylene Glycol
  • Glycerin
  • Preservative
  • Water

The resulting formula has a pH of 1 and is slightly sticky. I aim for a clear water essence texture. How can I reduce the stickiness and adjust the pH to a suitable range for skin application?

Answer

Formulation Feedback: Vitamin C and Lycopene Water Essence

Thank you for sharing your formulation. It's great that you've observed the stability of Vitamin C with the addition of Lycopene.

You've correctly identified the main issues: the very low pH (1) and the slight stickiness.

Analysis of Your Formula

  • High Vitamin C Concentration: Your formula uses L-Ascorbic Acid at 15%. L-Ascorbic Acid is inherently acidic, which explains the low pH of 1. High concentrations can also contribute to the sticky texture you're experiencing.
  • Lycopene: Lycopene is a powerful antioxidant and can help protect Vitamin C from oxidation, which is beneficial for stability. Your usage rate of 5% is within the typical recommended range (1-10%). The ratio of Vitamin C to Lycopene isn't the primary cause of the pH or stickiness issues; these are mainly due to the high concentration and nature of L-Ascorbic Acid itself.
  • pH Level: A pH of 1 is too low for cosmetic application and can cause significant skin irritation. For L-Ascorbic Acid to be effective and safe for skin, the optimal pH range is typically between 2.0 and 4.0. The FDA requires cosmetic products applied to the skin to have a pH of at least 3.5.

Recommendations to Address pH and Stickiness

To improve the formula's pH and texture while maintaining efficacy, consider the following adjustments, similar to the staff's suggestions:

  1. Reduce Vitamin C Concentration: Lowering the percentage of L-Ascorbic Acid will help increase the pH and reduce stickiness. A concentration of 10% is still highly effective for brightening and is a common level used in stable formulations.
  2. Incorporate Solvents/Carriers: Adding ingredients that help dissolve and carry the Vitamin C can improve texture and penetration. Options include:
    • Ethoxydiglycol: This acts as a solvent and carrier and can help reduce stickiness. The staff suggested 5%, but please note that current regulations limit Ethoxydiglycol usage to not more than 2.6% in leave-on skin products like a water essence. Using it within this limit can still be beneficial.
    • Ethyl Alcohol: Can help reduce stickiness but should be used sparingly (e.g., 5% as suggested by staff) as it can be drying to the skin.

Suggested Approach

A balanced approach could involve:

  • Reducing the Vitamin C (L-Ascorbic Acid) to 10%.
  • Adding Ethoxydiglycol (up to 2.6% for a leave-on product) and/or a small amount of Ethyl Alcohol (e.g., 5%) to improve texture and aid penetration.
  • Adjusting the water percentage accordingly.
  • Keeping Propylene Glycol, Glycerin, and the preservative at appropriate levels.
  • Maintaining Lycopene at 5% for its antioxidant benefits.

Remember to always check the pH of your final formulation and adjust it to be within the safe and effective range (ideally 3.5-4.0 for L-Ascorbic Acid) if necessary, although reducing the Vitamin C concentration should help raise it significantly from pH 1.

Performing stability testing on the adjusted formula is also crucial to ensure the Vitamin C remains potent over time.