Water Essence Formulation: Reducing Stickiness and Adjusting Low pH of High Concentration Vitamin C and Lycopene
Question
I have formulated a water essence with the following ingredients:
- L-Ascorbic Acid: 15%
- Lycopene: 5%
- Propylene Glycol
- Glycerin
- Preservative
- Water
The resulting formula has a pH of 1 and is slightly sticky. I aim for a clear water essence texture. How can I reduce the stickiness and adjust the pH to a suitable range for skin application?
Answer
Formulation Feedback: Vitamin C and Lycopene Water Essence
Thank you for sharing your formulation. It's great that you've observed the stability of Vitamin C with the addition of Lycopene.
You've correctly identified the main issues: the very low pH (1) and the slight stickiness.
Analysis of Your Formula
- High Vitamin C Concentration: Your formula uses L-Ascorbic Acid at 15%. L-Ascorbic Acid is inherently acidic, which explains the low pH of 1. High concentrations can also contribute to the sticky texture you're experiencing.
- Lycopene: Lycopene is a powerful antioxidant and can help protect Vitamin C from oxidation, which is beneficial for stability. Your usage rate of 5% is within the typical recommended range (1-10%). The ratio of Vitamin C to Lycopene isn't the primary cause of the pH or stickiness issues; these are mainly due to the high concentration and nature of L-Ascorbic Acid itself.
- pH Level: A pH of 1 is too low for cosmetic application and can cause significant skin irritation. For L-Ascorbic Acid to be effective and safe for skin, the optimal pH range is typically between 2.0 and 4.0. The FDA requires cosmetic products applied to the skin to have a pH of at least 3.5.
Recommendations to Address pH and Stickiness
To improve the formula's pH and texture while maintaining efficacy, consider the following adjustments, similar to the staff's suggestions:
- Reduce Vitamin C Concentration: Lowering the percentage of L-Ascorbic Acid will help increase the pH and reduce stickiness. A concentration of 10% is still highly effective for brightening and is a common level used in stable formulations.
- Incorporate Solvents/Carriers: Adding ingredients that help dissolve and carry the Vitamin C can improve texture and penetration. Options include:
- Ethoxydiglycol: This acts as a solvent and carrier and can help reduce stickiness. The staff suggested 5%, but please note that current regulations limit Ethoxydiglycol usage to not more than 2.6% in leave-on skin products like a water essence. Using it within this limit can still be beneficial.
- Ethyl Alcohol: Can help reduce stickiness but should be used sparingly (e.g., 5% as suggested by staff) as it can be drying to the skin.
Suggested Approach
A balanced approach could involve:
- Reducing the Vitamin C (L-Ascorbic Acid) to 10%.
- Adding Ethoxydiglycol (up to 2.6% for a leave-on product) and/or a small amount of Ethyl Alcohol (e.g., 5%) to improve texture and aid penetration.
- Adjusting the water percentage accordingly.
- Keeping Propylene Glycol, Glycerin, and the preservative at appropriate levels.
- Maintaining Lycopene at 5% for its antioxidant benefits.
Remember to always check the pH of your final formulation and adjust it to be within the safe and effective range (ideally 3.5-4.0 for L-Ascorbic Acid) if necessary, although reducing the Vitamin C concentration should help raise it significantly from pH 1.
Performing stability testing on the adjusted formula is also crucial to ensure the Vitamin C remains potent over time.
Related Products Mentioned
Vitamin C (L-ascorbic acid) (Ultra-Fine)
Ethoxydiglycol (e.q. Transcutol)
Propylene Glycol (USP)
Glycerin (USP/Food Grade)