(R)-Bis(3,5-di-tert-butylphenyl)(3',4'-dihydro-[1,1'-binaphthalen]-2-yl)phosphane

98%

  • Product Code: 229379
  CAS:    2749557-21-7
Molecular Weight: 664.94 g./mol Molecular Formula: C₄₈H₅₇P
EC Number: MDL Number:
Melting Point: Boiling Point: 694.0±55.0 °C(Predicted)
Density: Storage Condition: Room temperature, seal, inert gas
Product Description: Widely used as a chiral ligand in asymmetric catalysis, this compound plays a key role in enantioselective transformations such as hydrogenation, C–C bond formation, and cross-coupling reactions. Its bulky, sterically hindered structure enhances stereocontrol, making it particularly effective in rhodium- and ruthenium-catalyzed asymmetric hydrogenations of prochiral olefins and ketones. It is also employed in palladium-catalyzed reactions where high enantioselectivity is required. Due to its strong electron-donating properties and rigid chiral environment, it helps achieve high turnover numbers and excellent enantiomeric excess in pharmaceutical and fine chemical synthesis.
Sizes / Availability / Pricing:
Size Availability Price Quantity
0.050 10-20 days $297.92
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0.100 10-20 days $476.80
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(R)-Bis(3,5-di-tert-butylphenyl)(3',4'-dihydro-[1,1'-binaphthalen]-2-yl)phosphane
Widely used as a chiral ligand in asymmetric catalysis, this compound plays a key role in enantioselective transformations such as hydrogenation, C–C bond formation, and cross-coupling reactions. Its bulky, sterically hindered structure enhances stereocontrol, making it particularly effective in rhodium- and ruthenium-catalyzed asymmetric hydrogenations of prochiral olefins and ketones. It is also employed in palladium-catalyzed reactions where high enantioselectivity is required. Due to its strong electron-donating properties and rigid chiral environment, it helps achieve high turnover numbers and excellent enantiomeric excess in pharmaceutical and fine chemical synthesis.
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