(S)-2,2'-Bis((R)-4-(tert-butyl)-4,5-dihydrooxazol-2-yl)-1,1'-binaphthalene

97%

  • Product Code: 237489
  CAS:    155418-83-0
Molecular Weight: 504.66 g./mol Molecular Formula: C₃₄H₃₆N₂O₂
EC Number: MDL Number:
Melting Point: Boiling Point: 312.4±37.0 °C(Predicted)
Density: 1.410±0.06 g/cm3(Predicted) Storage Condition: 2-8°C, Sealed, Dry, Light-proof, Inert Gas
Product Description: Used as a chiral ligand in asymmetric catalysis, particularly in enantioselective transformations such as hydrogenation, allylic alkylation, and Diels-Alder reactions. Its rigid binaphthyl backbone and oxazoline rings provide a well-defined chiral environment, enabling high enantioselectivity when coordinated to transition metals like rhodium, ruthenium, or palladium. Commonly employed in the synthesis of pharmaceuticals and fine chemicals where control of stereochemistry is critical. The ligand’s steric bulk from the tert-butyl groups enhances selectivity by restricting approach of substrates to the metal center in a specific orientation.
Sizes / Availability / Pricing:
Size Availability Price Quantity
100mg 10-20 days ฿9,000.00
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250mg 10-20 days ฿15,300.00
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1g 10-20 days ฿50,670.00
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(S)-2,2'-Bis((R)-4-(tert-butyl)-4,5-dihydrooxazol-2-yl)-1,1'-binaphthalene
Used as a chiral ligand in asymmetric catalysis, particularly in enantioselective transformations such as hydrogenation, allylic alkylation, and Diels-Alder reactions. Its rigid binaphthyl backbone and oxazoline rings provide a well-defined chiral environment, enabling high enantioselectivity when coordinated to transition metals like rhodium, ruthenium, or palladium. Commonly employed in the synthesis of pharmaceuticals and fine chemicals where control of stereochemistry is critical. The ligand’s steric bulk from the tert-butyl groups enhances selectivity by restricting approach of substrates to the metal center in a specific orientation.
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