(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

96%

  • Product Code: 70431
  Alias:    (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine; (R,R)-Jacobson Ligand
  CAS:    135616-40-9
Molecular Weight: 546.83 g./mol Molecular Formula: C₃₆H₅₄N₂O₂
EC Number: MDL Number: MFCD00191800
Melting Point: 205-207 °C(lit.) Boiling Point:
Density: Storage Condition: room temperature
Product Description: This chemical is primarily utilized as a chiral ligand in asymmetric catalysis, particularly in enantioselective synthesis. It plays a significant role in facilitating reactions such as the asymmetric epoxidation of alkenes, where it helps produce optically active epoxides with high enantiomeric purity. These epoxides are valuable intermediates in the synthesis of pharmaceuticals, agrochemicals, and fine chemicals. Additionally, its robust structure and ability to form stable complexes with transition metals make it suitable for use in various catalytic processes, including hydrogenation and oxidation reactions. Its application extends to the development of advanced materials and coordination chemistry, where it aids in creating well-defined metal complexes for research and industrial purposes.
Product Specification:
Test Specification
Melting point 205 207?
PURITYHPLC 96 100%
SPECIFIC ROTATION A20DC1 CH2CL2 -310 -330?
APPEARANCE Yellow powder or crystals
PROTON NMR SPECTRUM Conforms to Structure
Sizes / Availability / Pricing:
Size (g) Availability Price Quantity
1.000 10-20 days ฿360.00
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-
5.000 10-20 days ฿870.00
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-
25.000 10-20 days ฿4,200.00
+
-
(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
This chemical is primarily utilized as a chiral ligand in asymmetric catalysis, particularly in enantioselective synthesis. It plays a significant role in facilitating reactions such as the asymmetric epoxidation of alkenes, where it helps produce optically active epoxides with high enantiomeric purity. These epoxides are valuable intermediates in the synthesis of pharmaceuticals, agrochemicals, and fine chemicals. Additionally, its robust structure and ability to form stable complexes with transition metals make it suitable for use in various catalytic processes, including hydrogenation and oxidation reactions. Its application extends to the development of advanced materials and coordination chemistry, where it aids in creating well-defined metal complexes for research and industrial purposes.
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