Samarium(II) iodide
0.1M in THF
Reagent
Code: #234667
CAS Number
32248-43-4
science Other reagents with same CAS 32248-43-4
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Molecular Information
Weight
404.17 g/mol
Formula
SmI₂
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Registry Numbers
MDL Number
MFCD00058873
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Storage & Handling
Storage
2~8℃, flammable area
description Product Description
Widely used in organic synthesis as a powerful reducing agent, especially in carbon-carbon bond-forming reactions. It promotes reductive couplings of carbonyl compounds, such as in the pinacol coupling and the reductive cyclization of diketones. It is also employed in the Barbier-type reactions, where it facilitates the formation of alcohols from carbonyls and alkyl halides under mild conditions. Its ability to mediate single-electron transfer processes makes it valuable for complex molecule synthesis, including natural products. Additionally, it finds use in dehalogenation reactions and the reduction of sulfoxides to sulfides.
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