(Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate
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Code: #147837
Alias
(Bicyclo[2.2.1]heptan-2,5-diene)[1,4-bis(diphenylphosphine)butane]rhodium(I)tetrafluoroborate
CAS Number
82499-43-2
blur_circular Chemical Specifications
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Molecular Information
Weight
708.32 g/mol
Formula
C₃₅H₃₆BF₄P₂Rh
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Registry Numbers
MDL Number
MFCD00075218
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Physical Properties
Melting Point
210 °C (dec.) (lit.)
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Storage & Handling
Storage
Room temperature
description Product Description
This rhodium(I) complex is used as a homogeneous catalyst precursor in organic synthesis, particularly in hydrogenation reactions. When combined with chiral ligands, it enables high enantioselectivity in the asymmetric reduction of prochiral alkenes, imines, and ketones, making it valuable for producing chiral intermediates in pharmaceuticals and fine chemicals. The phosphine ligand framework (dppb) enhances stability and selectivity, supporting efficient performance under mild conditions. It is commonly employed in academic and industrial research for synthesizing enantiopure compounds.
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