(R)-Bis(3,5-di-tert-butylphenyl)(3',4'-dihydro-[1,1'-binaphthalen]-2-yl)phosphane
98%
Reagent
Code: #229379
CAS Number
2749557-21-7
science Other reagents with same CAS 2749557-21-7
blur_circular Chemical Specifications
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Molecular Information
Weight
664.94 g/mol
Formula
C₄₈H₅₇P
thermostat
Physical Properties
Boiling Point
694.0±55.0 °C(Predicted)
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Storage & Handling
Storage
Room temperature, seal, inert gas
description Product Description
Widely used as a chiral ligand in asymmetric catalysis, this compound plays a key role in enantioselective transformations such as hydrogenation, C–C bond formation, and cross-coupling reactions. Its bulky, sterically hindered structure enhances stereocontrol, making it particularly effective in rhodium- and ruthenium-catalyzed asymmetric hydrogenations of prochiral olefins and ketones. It is also employed in palladium-catalyzed reactions where high enantioselectivity is required. Due to its strong electron-donating properties and rigid chiral environment, it helps achieve high turnover numbers and excellent enantiomeric excess in pharmaceutical and fine chemical synthesis.
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