(R)-Bis(3,5-di-tert-butylphenyl)(3',4'-dihydro-[1,1'-binaphthalen]-2-yl)phosphane

98%

Reagent Code: #229379
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CAS Number 2749557-21-7

science Other reagents with same CAS 2749557-21-7

blur_circular Chemical Specifications

scatter_plot Molecular Information
Weight 664.94 g/mol
Formula C₄₈H₅₇P
thermostat Physical Properties
Boiling Point 694.0±55.0 °C(Predicted)
inventory_2 Storage & Handling
Storage Room temperature, seal, inert gas

description Product Description

Widely used as a chiral ligand in asymmetric catalysis, this compound plays a key role in enantioselective transformations such as hydrogenation, C–C bond formation, and cross-coupling reactions. Its bulky, sterically hindered structure enhances stereocontrol, making it particularly effective in rhodium- and ruthenium-catalyzed asymmetric hydrogenations of prochiral olefins and ketones. It is also employed in palladium-catalyzed reactions where high enantioselectivity is required. Due to its strong electron-donating properties and rigid chiral environment, it helps achieve high turnover numbers and excellent enantiomeric excess in pharmaceutical and fine chemical synthesis.

shopping_cart Available Sizes & Pricing

Size Availability Unit Price Quantity
inventory 50mg
10-20 days ฿9,660.00
inventory 100mg
10-20 days ฿15,460.00
(R)-Bis(3,5-di-tert-butylphenyl)(3',4'-dihydro-[1,1'-binaphthalen]-2-yl)phosphane
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Widely used as a chiral ligand in asymmetric catalysis, this compound plays a key role in enantioselective transformations such as hydrogenation, C–C bond formation, and cross-coupling reactions. Its bulky, sterically hindered structure enhances stereocontrol, making it particularly effective in rhodium- and ruthenium-catalyzed asymmetric hydrogenations of prochiral olefins and ketones. It is also employed in palladium-catalyzed reactions where high enantioselectivity is required. Due to its strong electron-donating properties and rigid chiral environment, it helps achieve high turnover numbers and excellent enantiomeric excess in pharmaceutical and fine chemical synthesis.
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